Influence of the Water Content of the Solvent on the Product Distribution in the Electrohydrodimerization of 2-Cyclohexenones

DOI: 10.1002/hlca.19810640536

Source and publish data:

Helvetica Chimica Acta p. 1570 - 1574 (1981)

Update date:2022-09-26

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Authors:

Tissot, Paul

Surbeck, Jean-Paul

Guelacar, Fazil O.

Margaretha, Paul

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Article abstract of DOI:10.1002/hlca.19810640536

The product distribution of compounds 2, 3 and 4 formed in the electrohydrodimerization (EHD) of 1 was determined as function of the water content of the solvent (CH3CN).The presence of water favours the formation of the glycols 4 and reduces the relative amounts of 1,6-diketones 2 and hydroxyketones 3, as determined by GC./MS.-analysis.

Full text of DOI:10.1002/hlca.19810640536

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