Catalytic allylic oxidation with a recyclable, fluorous seleninic acid

DOI: 10.1021/ol036501h

Source and publish data:

Organic Letters p. 775 - 777 (2004)

Update date:2022-08-05

Topics:

Authors:

Crich, David

Zou, Yekui

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Article abstract of DOI:10.1021/ol036501h

In conjunction with iodoxybenzene as reoxidant perfluorooctylseleninic acid catalyzes the allylic oxidation of alkenes to enones in trifluoromethylbenzene at reflux in moderate to good yield. After a reductive workup with sodium metabisulfite, the catalyst is recovered by fluorous extraction in the form of bis(perfluorooctyl) diselenide, which, itself, serves as a convenient catalyst precursor.

Full text of DOI:10.1021/ol036501h

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