A New Synthesis of Benzylidene Acetals

DOI: 10.1002/hlca.19930760115

Source and publish data:

Helvetica Chimica Acta p. 211 - 221 (1993)

Update date:2022-07-30

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Authors:

Li, Chunbao

Vasella, Andrea

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Article abstract of DOI:10.1002/hlca.19930760115

Aryl-halo-diazirines react under basic conditions with 1,3-cis-, 1,2-cis, and 1,2-trans-diols to give acetals.Yields are high.Diastereoselectivities depend upon the diol and upon the reaction conditions.Thus, reaction of the 1,3-cis-diol 1 (Scheme 1) with

Full text of DOI:10.1002/hlca.19930760115

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