Decomplexation of (η-Arene)(η-cyclopentadienyl)iron(II) Hexafluorophosphates: a Convenient One-pot Arylation Procedure

DOI: 10.1039/P19940000197

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 197 - 202 (1994)

Update date:2022-08-02

Topics:

Authors:

Brown, Richard A.

Fernando, Sharon I. S.

Roberts, Roger M. G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19940000197

A study has been made of the relative merits of range of decomplexation reagents in the demetallation of <(η-arene)(η-cyclopentadienyl)Fe> salts. 1,8-Phenanthroline have good yields of the free ligand when simple arene complexes were used but did not demetallate more sterically hindered species.The reaction was found to be light sensitive.Bipyridine gave much lower yields.Potassium tert-butoxide in pyridine or DMSO was found to be an excellent demetallating agent even with sterically crowded complexes.A one-pot arylation procedure was developed and extended to include a number of important heterocyclic derivatives.The mechanism of these decomplexation reactions is briefly adressesd.

Full text of DOI:10.1039/P19940000197

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-(2'-chloroanilino)butan-1-ol

Cas No:51170-07-1

R&D Labs maybe for 51170-07-1

Kono Chem Co.,Ltd

website:http://www.konochem.com

Contact:86-29-86107037

Address:No.170 West Avenue,Xi’an 710082,China
Xiamen Goodhealth Pharmchem Co., Ltd.

Contact:0086-592-2097683

Address:404R No.2 54# Minzu Rd., Xiamen, China
ZHANGJIAGANG FREE TRADE ZONE YONG HAN INTERNATIONAL TRADING CO., LTD(expird)

Contact:86 512 57910558

Address:qianjin M road
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.

Contact:+86-512-6585 6968

Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China
Longhui qunfeng Chemical Co., Ltd

Contact:86-731-82173407

Address:South-east Industrial Park, Longhui County, Hunan Province, China

Relevant to this article

Doi:10.1016/0009-2614(91)87135-X
(1991)
Multi-path quenchers: Efficient quenching of common fluorophores

Doi:10.1021/bc200424r
(2011)
Homoisochromane derivatives with a basic side chain in the 1 position

Doi:10.1002/ardp.19733061210
(1973)
Doi:10.1246/cl.1977.1483
(1977)
Organocatalytic synthesis of (2S,3R)-3-hydroxy-3-methyl-proline (OHMePro), a component of polyoxypeptins, and relatives using OHMePro itself as a catalyst

Doi:10.1021/ol0706004
(2007)
Palladium-catalyzed aromatization of β-bromovinyl aldehydes with alkenes

Doi:10.1016/j.tet.2005.08.001
(2005)

Article Doi