Tetrahedron Letters p. 5639 - 5642 (1997)
Update date:2022-08-03
Topics:
Pierre, Marie-Clotilde
Cheze, Catherine
Vercauteren, Joseph
Deuterium-labeled procyanidins have been prepared by hemisynthesis from taxifolin in order to investigate their metabolism in human. The structures of the desired deuterated natural compounds B3 10D (R1 = D, R2 = H) and B4 13D (R1 = D, R2 = H) were proven by spectroscopic and physical properties means, including 2H NMR spectrum. By-products with unatural absolute configuration at some centers were also formed along the process and were characterised.
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Doi:10.1002/jlac.199719970621
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