Bulletin of the Chemical Society of Japan p. 2213 - 2218 (1989)
Update date:2022-07-29
Topics:
Takeda, Yoshihiko
Misawa, Hiroaki
Sakuragi, Hirochika
Tokumaru, Katsumi
9,10-Dicyanoanthracene(DCA)-sensitized isomerization of (E)- and (Z)-isomers of an oxime ether of 2-acetylnaphthalene (E-1 and Z-1, respectively) was investigated in benzene by means of steady irradiation and laser flash photolysis.The excited singlet DCA was effectively quenched by E-1 and Z-1 to afford exciplexes, decay of which gave DCA triplets or 1 triplets.The triplet state of 1 was proposed as the isomerization intermediate and the formation efficiency of 1 triplets was estimated from isomerization quantum yields.
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Doi:10.1039/DT9810002550
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