THE THIOXANTHONE SYSTEM AS A TEMPLATE IN FREE RADICAL RELAY CHLORINATION OF A STEROID

DOI: 10.1016/S0040-4039(00)95467-4

Source and publish data:

Tetrahedron Letters p. 3187 - 3188 (1987)

Update date:2022-08-03

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Authors:

Breslow, Ronald

Guo, Tao

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Article abstract of DOI:10.1016/S0040-4039(00)95467-4

The 3-α-cholestanyl ester of thioxanthone-3-carboxylic acid undergoes selective chlorination of the steroid C-9 carbon by a radical relay mechanism directed by the thioxanthone template.

Full text of DOI:10.1016/S0040-4039(00)95467-4

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