Synthesis, structural characterisation and reactivity of molybdenum half-sandwich complexes containing keto- and amido-phosphines

DOI: 10.1016/S0022-328X(02)02017-X

Source and publish data:

Journal of Organometallic Chemistry p. 15 - 22 (2003)

Update date:2022-08-05

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Authors:

Andrews, Christopher D.

Burrows, Andrew D.

Jeffery, John C.

Lynam, Jason M.

Mahon, Mary F.

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Article abstract of DOI:10.1016/S0022-328X(02)02017-X

The keto-functionalised N-pyrrolyl phosphine ligand PPh₂NC₄H₃{C(O)CH₃-2} L¹ reacts with [MoCl(CO)₃ (η⁵-C₅R₅)] (R = H, Me) to give [MoCl(CO)₂ (CO)

Full text of DOI:10.1016/S0022-328X(02)02017-X

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Product name:[Mo(CO)2(P(C₆H₅)2)CH₂C(O)N(C₆H₅)2(P(CH₃)(C₆H₅)2)(C₅H₅)]⁽¹⁺⁾*BF₄^(1-)=MoC₄₆H₄₀NO₃P₂BF₄

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