Chemistry Letters p. 1471 - 1472 (1984)
Update date:2022-08-03
Topics:
Bryce-Smith, Derek
Isaacs, Neil S.
Tumi, Seddeg O.
The solid complex formed from bromine and silver benzoate reacts with both arenes and alkenes to form aryl and alkyl benzoates, respectively.Highly unusual substituent effects are observed in the benzoyloxylations of arenes.Electron-withdrawing groups (e.g. -NO2, -CN,-CO-) on the aromatic ring facilitate reaction though directing the attacking reagent exclusively to the meta position.In alkanes, tertiary positions are most prone to attack.
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