Tetrahedron p. 833 - 842 (1981)
Update date:2022-08-03
Topics:
Addink, R.
Berends, W.
In the conversion of 1 to 2, a nonoxidative and a subsequent oxidative phase were distinguished.In the first phase the formation of the intermadiates 3,4 and 5 was established.In the second phase the formation of a dioxetane is postulated as the immediate precursor in the light giving step.The autoxidative chemiluminescence appeared to be a general feature of 8-substituted pteridines bearing a Me group at the 7-position.The chemiluminescence spectra and their quantum yields are determined.
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