Carbohydrate Research p. 141 - 149 (1974)
Update date:2022-08-03
Topics:
Bourne, Edward J.
Mckinley, Ian R.
Weigel, Helmut
The relative ease of formation of five-, six-, seven-, and eight-membered cyclic benzeneboronates is discussed. Pentane-1,3,5-triol forms, by interaction with benzene-boronic anhydride, exclusively DL-4-(2-hydroxyethyl)-2-phenyl-1,3,2-dioxaborinane. It is suggested that, in this compound, the oxygen atom of the hydroxyl group is intramolecularly co-ordinated with the boron atom.
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