Journal of the American Chemical Society p. 5112 - 5117 (1988)
Update date:2022-08-02
Topics:
Bertsch, Achim
Grimme, Wolfram
Reinhardt, Gerd
Rose, Hermann
Warner, Philip M.
The kinetics for the extrusion of benzene from norcaradiene adducts 11 and 12 have been measured.The high 11/12 rate ratio, 8.9E3, was shown to be due to homoaromatic interactions in the cycloreversion transition state emanating from 11.This conclusion was reached after studying the benzene extrusion kinetics for several model compounds, including 20.The syntheses of the requisite compounds are fully described.
View MoreShanghai SMEC Trading Co., Ltd.
website:http://www.shanghaismec.com
Contact:+86-21-68811293
Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA
website:http://www.cartoonchem.com/
Contact:+86-25-58074918
Address:Room 2109, RuiHua Business Center,315 South ZhongShan Road, Nanjing 210001, China
Shanghai Zhihua ChemTech Co., Ltd.
Contact:+86-13774313779
Address:Room 817 Suite B 3333 Shenjiang Road
Shanghai Mio Chemical Co., Ltd
Contact:0086 21- 64401188-622
Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Zhangjiagang Jianing Import & Export Co.,Ltd.
Contact:086-512-55379012 13913607595
Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
Doi:10.1021/acs.orglett.8b03658
(2019)Doi:10.1039/b809486a
(2008)Doi:10.1016/j.tetlet.2011.07.072
(2011)Doi:10.1016/0022-328X(88)80636-3
(1988)Doi:10.1016/S0040-4039(03)00241-7
(2003)Doi:10.1021/ja01629a103
(1955)