Synthesis of Pentafluoroethyl Trifluoroacetate by Low-Temperature Direct Fluorination

DOI: 10.1246/bcsj.66.2454

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2454 - 2456 (1993)

Update date:2022-08-03

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Authors:

Akimura, Takashi

Shibakami, Motonari

Tamura, Masanori

Kurosawa, Shigeru

Sekiya, Akira

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Article abstract of DOI:10.1246/bcsj.66.2454

Ethyl acetate was perfluorinated by direct fluorination in the presence of cesium fluoride, affroding pentafluoroethyl trifluoroacetate in excellent yield.In the reaction pathway, the dimerization of trifluoroacetyl fluoride with cesium fluoride gives pentafluoroethyl trifluoroacetate.

Full text of DOI:10.1246/bcsj.66.2454

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