Tetrahedron p. 3119 - 3126 (1974)
Update date:2022-08-05
Topics:
Dagonneau
Vialle
Grignard reagents react with thiobenzophenone to give mainly the compound resulting from addition of the' organic radical to the sulfur atom. Addition to carbon, double addition both to sulfur and to carbon, and formation of tetraphenylthiiranne are also observed. The stable alkylthiodiphenylmethyl radical has been detected in the reaction medium. A mechanism is proposed to account for the various reactions.
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Doi:10.1039/c7cy01435j
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