Journal of Inorganic and General Chemistry
ARTICLE
Zeitschrift für anorganische und allgemeine Chemie
vacuum. After 12 h, [CH3SO2NX3]+[SbF6]– (X = H, D), was obtained
Table 3. Crystal data and structure refinement for CH3SO2NH2 and
[CH3SO2NH3]+[Sb2F11]–.
as a colorless solid. The synthesis of [CH3SO2NH3]+[Sb2F11]– was car-
ried out by the reaction of 9 equiv. of SbF5 under analogous conditions.
The obtained colorless salts are stable up to room temperature.
CH3SO2NH2
[CH3SO2NH3]+[Sb2F11]–
Mr
95.12
orthorhombic
Pnma
9.9598(5)
7.4262(4)
5.3555(3)
90
548.63
monoclinic
P21/c
7.7391(3)
9.8130(3)
15.8449(6)
90
Crystal system
Space group
a /Å
b /Å
c /Å
Acknowledgements
Financial support of this work by the Ludwig-Maximilian-University
Munich (LMU) by the Deutsche Forschungsgemeinschaft (DFG) and
F-Select GmbH is gratefully acknowledged.
α /°
β /°
90
90
396.11(4)
4
1.595
0.637
0.71073
200
173(2)
–9:12; –9:8; –6:5
1518
96.024(4)
90
1196.68(7)
4
3.045
4.826
0.71073
1008
173(2)
–4:9; –12:11; –19:18
5947
2335
0.0252
165
γ /°
V /Å3
Keywords: Methanesulfonamide; Protonation; Superacid
chemistry; Vibrational spectroscopy; X-ray diffraction
Z
ρcalcd, /g·cm–3
μ /mm–1
λ(Mo-Kα) /Å
F(000)
References
T /K
hkl range
Refl. measured
Refl. unique
Rint
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© 0000 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Leitz, Dominik
