Journal of the American Chemical Society p. 6877 - 6881 (1983)
Update date:2022-08-03
Topics: Oxidation Yield NMR spectroscopy Catalyst Isolation Palladium-Catalyzed Reaction Conditions Cyclic Imines Enamines
Pugin, B.
Venanzi, L. M.
Amino alkenes of the type CH2=CH(CH2)nNH2 (n = 3,4) are cyclized to pyrrolines or piperideines under ''Wacker process''conditions.Amino alkenes with a secondary amino group yield the corresponding cyclic enamines, while tertiary amino alkenes give amino ketones.
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