Benzidine Rearrangements. 17. The Concerted Nature of the One-Proton p-Semidine Rearrangement of 4-Methoxyhydrazobenzene

DOI: 10.1021/ja00383a031

Source and publish data:

Journal of the American Chemical Society p. 5181 - 5184 (1982)

Update date:2022-07-29

Topics:

Authors:

Shine, Henry J.

Zmuda, Henryk

Kwart, Harold

Horgan, Ann Gafney

Breichbiel, Martin

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Article abstract of DOI:10.1021/ja00383a031

The nitrogen kinetic isotope effects (KIE) for the acid-catalyzed rearrangement of 4-methoxyhydrazobenzene (1b) into the p-semidine (4-methoxy-4'-aminodiphenylamine, 2b) and o-semidine (2-amino-5-methoxydiphenylamine, 3b) have been measured and are 1.0296

Full text of DOI:10.1021/ja00383a031

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