Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 372 - 375 (1991)
Update date:2022-08-04
Topics:
Gul'tyai, V. P.
Rubinskaya, T. Ya.
Mendkovich, A. S.
The electrolysis of 1-acetylnaphthalene at a controlled potential (DMF, Ba(ClO4)2) leads to the formation of 5-acetyl-1,2,4,5-tetrahydro-2-methyl-2-(1-naphthyl)-1,4-methano-3-benzoxepine (yield of 60percent); this is explained by the stabilization of the dimeric dianion of the "Head-tail" type by the Ba2+ cations.The formation of 2,3-dimethyl-2,3-di-(1-naphthyl)-butane-2,3-diol is observed with the acylotropic rearrangement of the intermediate anion, leading to 2-acetylnaphthalene, in the presenc of lithium cations.
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