ORIGINE DE L'ETAIN FORME DURANT LES ELECTROLYSES DU DICHLORURE DE METHYLPHENYLETAIN

Article abstract of DOI:10.1016/0022-328X(86)80171-1

Studies of electroreduction of methylphenyltin dichloride and dihydride enabled us to follow the formation of bis(chloromethylphenyltin).This dimer decays rapidly in the solid state.Migration of a phenyl group and disproportionation of the resulting chloromethyltin derivative initiated the formation of amalgamated tin and trisubstituted organotin compounds during electrolysis of the dichloride.