Bulletin of the Chemical Society of Japan p. 3285 - 3290 (1987)
Update date:2022-09-26
Topics:
Murahashi, Shun-Ichi
Mitsue, Yo
Tsumiyama, Tatsuo
The reaction of β-amino ketones with bis(acetonitrile)dichloropalladium(II) in the presence of triethylamine gives the corresponding enaminones regioselectively.The cyclic β-amino ketones can be converted into the corresponding exocyclic enaminones.The enaminones thus obtained are versatile synthetic intermediates.The reaction of (E)-enaminones with organocuprates gave the corresponding (E)-α,β-unsaturated ketones.
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