Tetrahedron p. 3859 - 3868 (1990)
Update date:2022-09-26
Topics:
Thoraval, J. Y.
Nagai, W.
Yeung Lam Ko, Y. Y. C.
Carrie, R.
Disubstituted diazo compounds rapidly add to P-chloro (bistrimethylsilyl) methylene phosphine at low temperature. 1H, 31P and 13C NMR allow the characterization of the resulting cycloadducts and the establisment of the stereochemistry of the resulting cycloadducts which are potential precursors of ?3λ5 bis methylene phosphorane by nitrogen extrusion.
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