Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature

DOI: 10.1021/ja035835z

Source and publish data:

Journal of the American Chemical Society p. 8704 - 8705 (2003)

Update date:2022-08-04

Topics:

Authors:

Roy, Amy H.

Hartwig, John F.

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Article abstract of DOI:10.1021/ja035835z

Aryl tosylates are attractive substrates for Pd-catalyzed cross-coupling reactions, but they are much less reactive than the more commonly used aryl triflates. We report the oxidative addition of aryl tosylates to Pd(PPF-t-Bu)[P(o-tolyl)₃] and

Full text of DOI:10.1021/ja035835z

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