Synthesis p. 1123 - 1125 (1985)
Update date:2022-09-26
Topics:
Angibeaud, Pierre
Defaye, Jacques
Gadelle, Andree
Utille, Jean-Pierre
Benzyl ether protective groups are oxidatively removed by ozone under relatively mild conditions.Reaction products are benzoic ester, benzoic acid, and the corresponding alcohol.Subsequent deacylation with sodium methoxide affords a convenient debenzylation technique which has been applied to various O-benzyl protected carbohydrates 1 to afford the deprotected species 2.Glycosides and acetals are unaffected by the treatment.
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(1940)
