Organic Letters p. 3483 - 3486 (2003)
Update date:2022-08-02
Topics:
Denmark, Scott E.
Kallemeyn, Jeffrey M.
Equation presented. A mild and general palladium-catalyzed insertion of 1,2-diethoxy-1,1,2,2-tetramethyldisilane into a variety of aryl bromides affords the aryldimethylsilyl ethers in high yields. Hydrolysis of the ethers under pH-optimized conditions results in the exclusive formation of the desired aryldimethylsilanols.
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