Reaction of Singlet Oxygen with Enamino Carbonyl Systems. A General Method for the Synthesis of α-Keto Derivatives of Lactones, Esters, Amides, Lactams, and Ketones

DOI: 10.1021/jo00219a025

Source and publish data:

Journal of Organic Chemistry p. 3573 - 3580 (1985)

Update date:2022-08-02

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Authors:

Wasserman, Harry H.

Ives, Jeffrey L.

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Article abstract of DOI:10.1021/jo00219a025

A general method for the introduction of a ketone α to the carbonyl group of a ketone, lactone. ester, substituted amide, or lactam has been developed involving the formation and dye-sensitized photooxygenation of enamino carbonyl intermediates.

Full text of DOI:10.1021/jo00219a025

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