Reaction of Singlet Oxygen with Enamino Carbonyl Systems. A General Method for the Synthesis of α-Keto Derivatives of Lactones, Esters, Amides, Lactams, and Ketones

DOI: 10.1021/jo00219a025

Source and publish data:

Journal of Organic Chemistry p. 3573 - 3580 (1985)

Update date:2022-08-02

Topics:

Authors:

Wasserman, Harry H.

Ives, Jeffrey L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00219a025

A general method for the introduction of a ketone α to the carbonyl group of a ketone, lactone. ester, substituted amide, or lactam has been developed involving the formation and dye-sensitized photooxygenation of enamino carbonyl intermediates.

Full text of DOI:10.1021/jo00219a025

Products guided by the article

Product name:Cyclohexanone, 2-[(dimethylamino)methylene]-3-methyl-6-(1-methylethyl)-, trans-

Cas No:61223-73-2

R&D Labs maybe for 61223-73-2

HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD

Contact:+86-571-88932183

Address:Hangzhou
zhuzhou zhongle chemical co. ltd.

Contact:+86-0731 28228409

Address:Zhuzhou, Hunan, China
Hangzhou Share Chemical Co., Ltd(expird)

Contact:+86-57187093700

Address:Hang Xing Road
Jai Radhe Sales

website:http://www.jairadhesales.com

Contact:0091-79-26431096

Address:309 Harikrupa Tower,Nr old Sharda Mandir Char Rasta,Ellisbridge
Tianjin Realet Chemical Technology Co.,Ltd.

website:http://www.realetchem.com

Contact:+86-022-58788819

Address:shuanggang industrial park

Relevant to this article

Sterically Shielded, Stabilized Nitrile Imine for Rapid Bioorthogonal Protein Labeling in Live Cells

Doi:10.1021/jacs.8b00126
(2018)
Synthesis, spectral, and antifungal activity of Ru(II) mixed-ligand complexes

Doi:10.1081/SIM-120021656
(2003)
Manipulating L-aspartic and L-glutamic acids - Diastereoselective synthesis of enantiopure β-amino-γ-hydroxy acids and γ-amino-δ-hydroxy acids

Doi:10.1002/ejoc.200300199
(2003)
Synthesis and absolute structure of (-)-umtatin

Doi:10.1246/bcsj.81.863
(2008)
Synthesis of 2-(4-aminophenyl)ethyl 3-deoxy-5-O-(3,4,6-tri-O-β-D-glucopyranosyl-α-D-glucopyranosyl)-α-D-manno-oct-2-ulopyranosidonic acid, a highly branched pentasaccharide corresponding to structures found in lipopolysaccharides from Moraxella catarrhalis

Doi:10.1016/0008-6215(95)00269-3
(1995)
SPIN TRAPPING REACTIONS WITH NITRIC OXYDES, I. DIALKYL NITROXYDES

Doi:10.1016/S0040-4039(00)83873-3
(1986)

Article Doi