Tetrahedron Letters p. 4741 - 4744 (1997)
Update date:2022-08-04
Topics:
Chen, Shu-Hui
Stille vinylation reactions involving α-styryltrimethyltin 3b and a series of chloro- or bromo-pyridine derivatives are described. In contrast to the rare cine selectivity observed with iodobenzene 10a or 3-iodotoluene 10b, reactions between vinyltin 3b and a series of 2-halopyridine derivatives 15(a-d) yield 1,1-disubstituted ipso-coupled olefins 16(a-d) as the predominant products.
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