Journal of Organic Chemistry p. 104 - 119 (2019)
Update date:2022-08-05
Topics:
Chaudhary, Priyanka
Gupta, Surabhi
Muniyappan, Nalluchamy
Sabiah, Shahulhameed
Kandasamy, Jeyakumar
Regioselective ring nitration of N-alkyl anilines is reported using tert-butyl nitrite. The reactions proceed efficiently with a wide range of substrates providing synthetically useful N-nitroso N-alkyl nitroanilines in excellent yields which can be easily converted into N-alkyl phenylenediamines and N-alkyl nitroanilines using Zn-AcOH and HCl/MeOH, respectively.
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