Journal of Organic Chemistry p. 2266 - 2270 (1983)
Update date:2022-08-03
Topics:
Jain, Subhash C.
Dussourd, David E.
Conner, William E.
Eisner, Thomas
Guerrero, Angel
Meinwald, Jerrold
In our earlier study of the female sex attractant from an arctiid moth (Utetheisa ornatrix), the occurence of an uncharacterized C-21 tetraene was noted along with (Z,Z,Z)-3,6,9-heneicosatriene, the major pheromone constituent.The sex attractant glands of females from other populations of this moth have now yielded this C-21 tetraene as a major component, accompanied by a new C-21 diene.Spectral and chemical studies of these two EAG-active compounds led to their characterization as (Z,Z,Z)-1,3,6,9-heneicosatetraene and (Z,Z)-6,9-heneicosadiene.These structures and configurations were confirmed by synthesis.
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