Organic Letters p. 43 - 46 (2004)
Update date:2022-08-02
Topics:
Diaz, David D.
Finn
(Equation presented) Formamidine ureas display a rich manifold of reactivity. Thiols induce substitution at the carbonyl carbon to give thiolcarbamates; base-mediated alkylation and acylation occurs at the terminal urea nitrogen, and a new fragmentation/acylation pathway has been uncovered with isocyanates.
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