Bulletin of the Chemical Society of Japan p. 277 - 281 (1995)
Update date:2022-08-03
Topics:
Komatsu, Toshiki
Tsuchiya, Masahiro
Furusawa, Gen-ichi
Kuriyama, Yasunao
Sakugari, Hirochika
et al.
Pulsed laser excitation of contact charge transfer pairs of hexamethylbenzene (HMB) and oxygen in methanol-acetonitrile gave no evidence for intermediacy of reactive species such as HMB radical cations and penthamethylbenzyl cations (ArCH2+), though stationary irradiation of the pair in hydroxylic solvents afforded distinct products arising from the cationic species.The mechanism of reactions was discussed in comparison with 9,10-dicyanoanthracene-sensitized oxygenation of HMB.
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