Inorganic Chemistry p. 862 - 865 (1964)
Update date:2022-09-26
Topics: Ligand Boron Organic synthesis Coordination Chemistry
Malhotra
Tetrakis(dimethylamino)diboron reacts with certain protonic acids to give substituted diboron compounds. With hydrogen sulfide, a six-membered ring compound containing two boron-boron bonds is formed. Hydrogen cyanide, chloride, and bromide react to yield tetrasubstituted products which are stabilized by dimethylamine molecules firmly attached to the boron atoms by coordination linkages. The physical and chemical properties characterizing these compounds are given and structures are discussed.
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