ONE-STEP SYNTHESIS OF KETONES FROM CARBOXYLIC ACIDS AND GRIGNARD REAGENTS IN THE PRESENCE OF A NICKEL(II)-PHOSPHINE CATALYST.

DOI: 10.1016/S0040-4039(00)88199-X

Source and publish data:

Tetrahedron Letters p. 3677 - 3680 (1983)

Update date:2022-08-05

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Authors:

Fiandanese, V.

Marchese, G.

Ronzini, L.

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Article abstract of DOI:10.1016/S0040-4039(00)88199-X

A one-step synthesis of diaryl and alkyl-aryl ketones by the reaction of carboxylic acid with Grignard reagents in the presence of NiCl2(Ph2PCH2CH2PPh2) as catalyst is described.In the nickel-catalyzed Grignard reaction the formation of alcohols is nearly completely suppressed.

Full text of DOI:10.1016/S0040-4039(00)88199-X

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