Tetrahedron Letters p. 2737 - 2740 (1987)
Update date:2022-07-30
Topics:
Minami, Ichiro
Yuhara, Masami
Tsuji, Jiro
As a new protective group of amines, 1-isopropylallyloxycarbonyl (IPAoc) group was developed.IPAoc group can be removed by treatment with a palladium-phosphine catalyst forming carbon dioxide and 4-methyl-1,3-pentadiene by the decarboxylation and β-hydrogen elimination of (?-1-isopropylallyl)-palladium intermediate under neutral condititons.The present protection-deprotection was applied to a one-pot peptide synthesis.
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Doi:10.1016/S0957-4166(03)00530-5
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(2011)Doi:10.1021/ic010272i
(2001)Doi:10.1007/BF01158505
()Doi:10.1016/S0960-894X(02)00310-4
(2002)Doi:10.1021/ja00863a012
(1962)
