Identification of a Further Transient Species relating to Rhodium-complex Catalysed Asymmetric Hydrogenation

DOI: 10.1039/c39830000664

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 664 - 666 (1983)

Update date:2022-08-02

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Authors:

Brown, John M.

Chaloner, Penny A.

Morris, Gareth A.

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Article abstract of DOI:10.1039/c39830000664

Interconversion of the diastereoisomeric rhodium enamide complexes (1) and (2) occurs by an intramolecular mechanism requiring an olefin dissociated species (3).

Full text of DOI:10.1039/c39830000664

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