UNUSUAL REGIOSELECTIVE HYDROSILYLATION OF ETHYNYLMETHYLDICHLOROSILANE WITH DIMETHYILCHLOROSILANE CATALYZED BY TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM(O)

DOI: 10.1246/cl.1982.1663

Source and publish data:

Chemistry Letters p. 1663 - 1666 (1982)

Update date:2022-07-29

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Authors:

Matsumoto, Hideyuki

Hoshino, Yoshikazu

Nagai, Yoichiro

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Article abstract of DOI:10.1246/cl.1982.1663

The hydrosilylation of ethynylmethyldichlorosilane with dimethylchlorosilane catalyzed by tetrakis(triphenylphosphine)platinum(O) was found to show quite an unusual regioselectivity to afford the geminal product, 1-(methyldichlorosilyl)-1-(dimethylchlorosilyl)ethene, almost exclusively.

Full text of DOI:10.1246/cl.1982.1663

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