Chemistry Letters p. 1663 - 1666 (1982)
Update date:2022-07-29
Topics:
Matsumoto, Hideyuki
Hoshino, Yoshikazu
Nagai, Yoichiro
The hydrosilylation of ethynylmethyldichlorosilane with dimethylchlorosilane catalyzed by tetrakis(triphenylphosphine)platinum(O) was found to show quite an unusual regioselectivity to afford the geminal product, 1-(methyldichlorosilyl)-1-(dimethylchlorosilyl)ethene, almost exclusively.
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