The Nitration of Acylpentamethylbenzenes and 1,3-Diacyltetramethylbenzenes Bearing, as the Acyl Components, Pivaloyl, Trichloroacetyl, and Tribromoacetyl Groups. Exclusive Attack on the Methyl Group at the Most Crowded Site

DOI: 10.1246/bcsj.54.1186

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1186 - 1190 (1981)

Update date:2022-07-29

Topics:

Authors:

Suzuki, Hitomi

Hashihama, Mitsuyuki

Mishina, Tadashi

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Article abstract of DOI:10.1246/bcsj.54.1186

When treated with concentrated nitric acid in dichloromethane at room temperature, the title compounds undergo an exclusive attack on the methyl group at the most crowded site, giving 6-acyl-2,3,4,5-tetramethylbenzyl nitrates, and 2,6-diacyl-3,4,5-trimeth

Full text of DOI:10.1246/bcsj.54.1186

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