Stereospecific Synthesis of 1,4-Dienes by Cross-Coupling of Allyl Halides with Alkenylcopper Intermediates from Alkenyldialkylboranes

DOI: 10.1021/jo01291a046

Source and publish data:

Journal of Organic Chemistry p. 550 - 552 (1980)

Update date:2022-08-04

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Authors:

Brown, Herbert C.

Campbell, James B.

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Article abstract of DOI:10.1021/jo01291a046

Alkenylcopper intermediates, generated from alkenyldialkylborane derivatives of 9-borabicyclo<3.3.1>nonane (9-BBN) and dicyclohexylborane (DCB), undergo stereospecific cross-coupling with allylic halides to yield stereodefined 1,4-dienes.

Full text of DOI:10.1021/jo01291a046

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