Stereospecific Synthesis of 1,4-Dienes by Cross-Coupling of Allyl Halides with Alkenylcopper Intermediates from Alkenyldialkylboranes

DOI: 10.1021/jo01291a046

Source and publish data:

Journal of Organic Chemistry p. 550 - 552 (1980)

Update date:2022-08-04

Topics:

Authors:

Brown, Herbert C.

Campbell, James B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01291a046

Alkenylcopper intermediates, generated from alkenyldialkylborane derivatives of 9-borabicyclo<3.3.1>nonane (9-BBN) and dicyclohexylborane (DCB), undergo stereospecific cross-coupling with allylic halides to yield stereodefined 1,4-dienes.

Full text of DOI:10.1021/jo01291a046

Products guided by the article

Product name:((E)-3,3-Dimethyl-penta-1,4-dienyl)-benzene

Cas No:72161-18-3

R&D Labs maybe for 72161-18-3

Shanghai Maxchemco Chemical Industry Co., Ltd.

Contact:(86)21-51079223

Address:No.1305-8, B241, the Ecust Park, Huajing Road, Xuhui District, Shanghai
SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD

website:http://www.jinjingroup.com

Contact:86-574-13989382828

Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China
Winchem Industrial Co. Ltd.(expird)

Contact:86-574-83851061 86-574-87083208

Address:Room 905, No.3 Building,East Business Center, 456 Xingning Road, Ningbo City,China
CHEM PLUS

Contact:0027-717-456976

Address:2ND FLOOR, 325 VAUSE ROAD, OVERPORT, 4001, SOUTH AFRICA
Dalian Join King Biochemical Tech. Co., Ltd.

Contact:0411 39216206

Address:814 First State Blvd

Relevant to this article

A New Route of the Isoindole Nucleus via Furan-Pyrrole Ring-Exchange

Doi:10.1039/c39940001535
(1994)
Synthesis of iodinated and radioiodinated (E)-N-(3-iodoprop-2-enyl)-2β-carbomethoxy-3β-(3',4'-dichlorophenyl) notropane (β-CDIT): A ligand for the dopamine transporter

Doi:10.1002/(SICI)1099-1344(199709)39:9<757::AID-JLCR24>3.0.CO;2-J
(1997)
Ring Transformations and Amination in Reactions of 3-Halogeno-5-phenyl-1,2,4-triazines with Potassium Amide in Liquid Ammonia

Doi:10.1021/jo01293a022
(1980)
Catalytic acceptorless dehydrogenations: Ru-Macho catalyzed construction of amides and imines

Doi:10.1016/j.tet.2014.03.085
(2014)
Doi:10.1111/j.1746-1561.2002.tb06531.x
(1959)
Donor-acceptor (D-A)-substituted polyyne chromophores: Modulation of their optoelectronic properties by varying the length of the acetylene spacer

Doi:10.1002/chem.201301642
(2013)

Article Doi