
Journal of the Chemical Society. Chemical communications p. 1443 - 1445 (1987)
Update date:2022-09-26
Topics:
Ishibashi, Hiroyuki
Nakatani, Hiroshi
Maruyama, Kazumi
Minami, Kenjiro
Ikeda, Masazumi
α-Trimethylsilyl-substituted sulphoxides and sulphides undergo rearrangement with loss of the silyl group when treated respectively with trifluoroacetic anhydride and with N-halogenosuccinimide in the presence of trifluoroacetic acid, giving α-acyloxy sulphides and α-halogeno sulphides.
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