Desilylative Pummerer-like Rearrangement of α-Trimethylsilyl-substituted Sulphoxides and Sulphides: Formation of α-Acyloxy and α-Halogeno Sulphides

DOI: 10.1039/c39870001443

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1443 - 1445 (1987)

Update date:2022-09-26

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Authors:

Ishibashi, Hiroyuki

Nakatani, Hiroshi

Maruyama, Kazumi

Minami, Kenjiro

Ikeda, Masazumi

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Article abstract of DOI:10.1039/c39870001443

α-Trimethylsilyl-substituted sulphoxides and sulphides undergo rearrangement with loss of the silyl group when treated respectively with trifluoroacetic anhydride and with N-halogenosuccinimide in the presence of trifluoroacetic acid, giving α-acyloxy sulphides and α-halogeno sulphides.

Full text of DOI:10.1039/c39870001443

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