Journal of the Chemical Society. Chemical communications p. 1470 - 1472 (1983)
Update date:2022-09-26
Topics:
Hiroi, Kunio
Kitayama, Ryuichi
Sato, Shuko
Dramatic solvent effects were observed in the thermolysis of allyl sulphinates; heating of chiral trans- and cis-allyl sulphinates (S)-(-)-(1a - g) in N,N-dimethylformamide at 90 - 120 deg C provided chiral sulphones (2a - d) in good yields with very high stereospecificity.
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