Dramatic Solvent Effects and Stereospecificity in Allylic Sulphinate-Sulphone Rearrangements

DOI: 10.1039/c39830001470

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1470 - 1472 (1983)

Update date:2022-09-26

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Authors:

Hiroi, Kunio

Kitayama, Ryuichi

Sato, Shuko

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Article abstract of DOI:10.1039/c39830001470

Dramatic solvent effects were observed in the thermolysis of allyl sulphinates; heating of chiral trans- and cis-allyl sulphinates (S)-(-)-(1a - g) in N,N-dimethylformamide at 90 - 120 deg C provided chiral sulphones (2a - d) in good yields with very high stereospecificity.

Full text of DOI:10.1039/c39830001470

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