Dramatic Solvent Effects and Stereospecificity in Allylic Sulphinate-Sulphone Rearrangements

DOI: 10.1039/c39830001470

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1470 - 1472 (1983)

Update date:2022-09-26

Topics:

Authors:

Hiroi, Kunio

Kitayama, Ryuichi

Sato, Shuko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39830001470

Dramatic solvent effects were observed in the thermolysis of allyl sulphinates; heating of chiral trans- and cis-allyl sulphinates (S)-(-)-(1a - g) in N,N-dimethylformamide at 90 - 120 deg C provided chiral sulphones (2a - d) in good yields with very high stereospecificity.

Full text of DOI:10.1039/c39830001470

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1-methyl-4-((1-phenylallyl)sulfonyl)benzene

Cas No:73082-84-5

R&D Labs maybe for 73082-84-5

Hongyi Import & Export CO.,LTD

Contact:86-13319649499

Address:Nanzheng Neighborhood Commitees, Chongwen Office, Yongding District
Langchem

Contact:+86+21-58956006 15800617331

Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
QINGDAO ON-BILLION INDUSTRAIL CO.,LTD

website:http://www.obn.com.cn

Contact:+86-15005320811 +86-532-80681989

Address:F35 Parkson Mansion No.44-60 Zhongshan Rd.
Hangzhou TJM Chemical Trade Co., Ltd

Contact:86-571-88223276 86-13388481653

Address:2221#,Boyuexuan,1860# Binsheng Road,Binjiang District, Hangzhou CityZhejiang Province, 310051, P. R. China
Shanghai Sunwise Chemical Co., Ltd

website:http://www.sunwisechem.com

Contact:86-021-33883180

Address:Room 10E, Building G, Westlink Center, No. 2337 Gudai Road, Minhang District, Shanghai, China PC: 201100

Relevant to this article

Hydrogen-Free Cobalt-Rhodium Heterobimetallic Nanoparticle-Catalyzed Reductive Amination of Aldehydes and Ketones with Amines and Nitroarenes in the Presence of Carbon Monoxide and Water

Doi:10.1021/acscatal.5b01198
(2015)
Characterization of route specific impurities found in methamphetamine synthesized by the Leuckart and reductive amination methods

Doi:10.1021/ac9005588
(2009)
Synthesis of reduction-sensitive 1,1-diarylhydrazines from 1,1-diarylamines

Doi:10.1139/cjc-2014-0132
(2014)
Stereochemical Course of the Haworth-Type Synthesis of Optically Active 2-(1-Methylpropyl)naphthalene

Doi:10.1021/jo01301a007
(1980)
Solvent effects on aza-anionic cycloaromatization of 2-(2-substituted-ethynyl)benzonitriles

Doi:10.1002/jccs.200100035
(2001)
Organometallic complexes of benzannelated phospholyls: Synthesis and characterization of benzophospholyl and the first iso-benzophospholyl metal complexes

Doi:10.1021/om040022k
(2004)

Article Doi