
Tetrahedron Letters p. 4673 - 4676 (1982)
Update date:2022-08-03
Topics:
Oppolzer, Wolfgang
Strauss, Heinrich F.
Simmons, Dana P.
(+/-)-Sinularene (1) as well as (+/-)-5-epi-sinularene (9) were synthesised in a stereocontrolled manner from the norbornene 2 in overall yields of 4 percent and 8 percent, respectively.The key step 5 <*> 6 involves a regio- and stereoselective intramolecular "magnesium-ene" reaction.
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