Characterization and catalytic activity of trans-[Pd(COCH2CH3)(TsO)(PPh3)2 ], isolated from the hydro-methoxycarbonylation of ethene catalyzed by [Pd(TsO)2(PPh3)2]

DOI: 10.1016/j.molcata.2004.04.014

Source and publish data:

Journal of Molecular Catalysis A: Chemical p. 233 - 240 (2004)

Update date:2022-08-02

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Authors:

Cavinato, Gianni

Toniolo, Luigi

Vavasori, Andrea

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Article abstract of DOI:10.1016/j.molcata.2004.04.014

trans-[Pd(COCH₂CH₃)(TsO)(PPh₃)₂] (I) was isolated after running the hydro-methoxycarbonylation (HMC) of ethylene. Complex (I) catalyzed the HMC of ethylene to methylpropanoate. Catalysis occurred via an initial

Full text of DOI:10.1016/j.molcata.2004.04.014

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