Metal Complexes of Sulphur Ligands. Part 20. Reaction of Bis(dimethylphenylphosphine)bis(monothiobenzoato)ruthenium(II) with some Bidentate Nitrogen-donor Lewis Bases and X-Ray Structural Analyses on Two Isomers of Bis(dimethylphenylphosphine)bis(monothiobenzoato)(1,10-phenanthroline...

DOI: 10.1039/DT9800000804

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 804 - 809 (1980)

Update date:2022-08-04

Topics:

Authors:

Gould, Robert O.

Stephenson, T. Anthony

Thomson, Mary A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9800000804

Reaction of (1) with ethylenediamine (en) in ethanol (1 : 1 molar ratio) gives (3), shown by i.r., (1)H and (31)P-<(1)H> n.m.r. studies to contain trans-S-bonded -SCOPh and cis-PMe2Ph groups.Reaction of (1) with 2,2'-bipyridyl (bipy) or 1,10-phenanthroline (phen) also gives the six-co-ordinate complexes but spectroscopic and X-ray analyses (for N-N = phen) reveal that the major product has the cis,cis,cis configuration (4).The crystals are monoclinic, space group P2₁/c, with a = 15.710(1), b = 13.729(2), c = 17.482(2) Angstroem, and β = 90.79(1).A minor product shown by X-ray analysis to bis cis,cis,trans- (5) is also formed.The crystals are monoclinic, space group P2₁/c, with a = 16.896(4), b = 10.754(2), c = 21.332(2) Angstroem, and β = 94.92(1).

Full text of DOI:10.1039/DT9800000804

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2,2'-bipyridylbis(dimethylphenylphosphine)bis(monothiobenzoato)ruthenium(II)

Cas No:74215-93-3

R&D Labs maybe for 74215-93-3

Shanxi Sanwei Group Co.,Ltd

Contact:0086-357-6662688

Address:Zhaocheng town, Hongtong County, Linfen City, Shanxi Province
Nanjing Capatue Chemical Co., Ltd

Contact:+86-25-86371192 +86-025-85720158

Address:No.20 Jiangjun Avenue, Jiangning Economic & Technical Development Zone
Beijing Mediking Biopharm Co., Ltd.

Contact:+86-10-89753524/81760121/81769521

Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China
taicang liyuan chemical co,.ltd

website:http://www.tcliyuanchem.com/productse.php

Contact:86-512-53539583

Address:Room 804,Huaxu Building,No.95,Renmin South Road,Taicang city,Jiangsu Province,China
Jiangxi Dongbang Pharmaceutical Co., Ltd.

Contact:+86-795-4433603, 4433388

Address:Fengxin Industrial Park, Fengxin County, Jiangxi Province, P.R.C

Relevant to this article

Synthesis of novel side-chain triphenylamine polymers with azobenzene moieties via RAFT polymerization and investigation on their photoelectric properties

Doi:10.1002/pola.26167
(2012)
Facile synthesis of thioamides via P₂S₅-mediated beckmann rearrangement of oximes

Doi:10.1002/cjoc.201200448
(2012)
Isocyanurates with planar chirality: Design, optical resolution, and isomerization

Doi:10.1002/chir.22093
(2012)
1,7-octadiene-assisted tandem multicomponent cross-enyne metathesis (CEYM)-diels-alder reactions: A useful alternative to Mori's conditions

Doi:10.1002/chem.201200835
(2012)
Selective and effective stabilization of Mo^VI=O Bonds by NH...S hydrogen bonds via trans influence

Doi:10.1021/ic301597d
(2012)
(R)-2-(3-mercapto-2(S)-methyl-1-oxo-propoxy)-3-(methylthio)propanoic acid, the first ultra-short-acting angiotensin converting enzyme inhibitor [2]

Doi:10.1021/jm00098a019
(1992)

Article Doi