STEREOSELECTIVE PHOTOSOLVOLYSES OF ipso-ACETOXYNITRO-ADDUCTS OF p-XYLENE

DOI: 10.1016/S0040-4039(00)93632-3

Source and publish data:

Tetrahedron Letters p. 91 - 94 (1980)

Update date:2022-08-05

Topics:

Authors:

Shosenji, Hideto

Esaki, Kensaku

Yamada, Kimiho

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Article abstract of DOI:10.1016/S0040-4039(00)93632-3

Diastereoisomers of 1,4-dimethyl-4-nitro-2,5-cyclohexadienyl acetate exchanged acetoxyls for alkoxyls on irradiation in alcohols to give the diastereoisomers of alkyl 1,4-dimethyl-4-nitro-2,5-cyclohexadienyl ethers in isomer ratios of 70:30, whereas the irradiation in pentane yielded p-xylene.

Full text of DOI:10.1016/S0040-4039(00)93632-3

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