Journal of the American Chemical Society p. 2681 - 2686 (1980)
Update date:2022-08-05
Topics:
Katsuhara, Yutaka
DesMarteau, Darryl D.
The reactions of chlorine(I) and bromine(I) trifluoromethanesulfonates with a variety of perfluoroalkyl halides are reported.The reactions form Br2, Cl2, or BrCl and the corresponding trifluoromethanesulfonate derivatives of the alkyls in good yields.Twelve new esters are reported and characterized.An SEi-type mechanism for the reactions is proposed with complete retention of configuration by the alkyl on substitution.
View MoreHebei Lead Bio-Chemicals Co., Ltd.
website:http://www.ldbiochem.com
Contact:+86-311-87826503
Address:481, Heping West Road, Shijiazhuang,China
Contact:+86-0592 5353131
Address:No.56 Guani Road Software Park 2,Siming District
website:http://www.lonwinchem.com
Contact:Tel: 86-21-59858395
Address:No#966,Huaxu Road,Shanghai 201702,P.R.China
Contact:86-25-84683399
Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
Contact:86-28-61993785
Address:No.70-13-21, North Section, Erhuan
Doi:10.1016/j.tet.2007.03.144
(2007)Doi:10.1039/j19690001378
(1969)Doi:10.1021/ja01562a050
(1957)Doi:10.1021/jo01310a010
(1980)Doi:10.1246/bcsj.60.563
(1987)Doi:10.1021/ol061022e
(2006)
