Journal of the American Chemical Society p. 2681 - 2686 (1980)
Update date:2022-08-05
Topics:
Katsuhara, Yutaka
DesMarteau, Darryl D.
The reactions of chlorine(I) and bromine(I) trifluoromethanesulfonates with a variety of perfluoroalkyl halides are reported.The reactions form Br2, Cl2, or BrCl and the corresponding trifluoromethanesulfonate derivatives of the alkyls in good yields.Twelve new esters are reported and characterized.An SEi-type mechanism for the reactions is proposed with complete retention of configuration by the alkyl on substitution.
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