Journal of the American Chemical Society p. 2681 - 2686 (1980)
Update date:2022-08-05
Topics:
Katsuhara, Yutaka
DesMarteau, Darryl D.
The reactions of chlorine(I) and bromine(I) trifluoromethanesulfonates with a variety of perfluoroalkyl halides are reported.The reactions form Br2, Cl2, or BrCl and the corresponding trifluoromethanesulfonate derivatives of the alkyls in good yields.Twelve new esters are reported and characterized.An SEi-type mechanism for the reactions is proposed with complete retention of configuration by the alkyl on substitution.
View MoreContact:+86-27-85733560
Address:NO.308,QINGNIAN RD.,WUHAN,CHINA
YanCheng LongShen Chemical Co.,Ltd.
Contact:+86-515-86668866
Address:No.13,Weiyi Road,Funing Aoyang Industrial Park
Taizhou Sunny Chemical Co.,Ltd
Contact:+86-523-86920899 +86-13951172783
Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China
Wuhan Soleado Technology Co.,Ltd.
Contact:86-2783341481 18971291927
Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China
Hangzhou LINGEBA Technology Co., Ltd.
Contact:+0086-571-87389059
Address:Office 1-913,NewYouth Plaza, GongShu Area, HangZhou,ZheJiang,P.R.China
Doi:10.1016/j.tet.2007.03.144
(2007)Doi:10.1039/j19690001378
(1969)Doi:10.1021/ja01562a050
(1957)Doi:10.1021/jo01310a010
(1980)Doi:10.1246/bcsj.60.563
(1987)Doi:10.1021/ol061022e
(2006)
