Journal of the Chemical Society. Perkin transactions I p. 2920 - 2926 (1981)
Update date:2022-07-29
Topics:
Murphy, William S.
Wattanasin, Sompong
Aryl cyclopropyl ketones (2) cyclise to 1-tetralones (3) in the presence of a variety of acid catalysts under mild conditions.Open-chain carbinols (4) are also formed.The ratio of (3) to (4) is dependent on the aryl ring substituents.A cationic mechanism is proposed.Cyclopropyl ketones (1) do not react.Stereoelectronic factors involved in the reactivity of the rigig cyclopropyl ketone (12) are discussed.The reactions of selected phenolic cyclopropyl ketones have been investigated as anionic counterparts to the acid-catalysed reactions.No reaction is observed.
View MoreContact:+86-571-87010026
Address:202, Zhenhua Road,
WEIFANG DERUN CHEMICAL CO.,LTD
Contact:86-536-8956886
Address:weifang
Suzhou Jingye Medicine & Chemical Co., Ltd
Contact:+86-512-66658588
Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China
website:https://www.yurisolar.com/en
Contact:86--18092602675
Address:No. 560, East Hangtian Road, Xi'an, China
Shenzhen HwaGen Pharmaceutical Co., Ltd
website:http://www.rafflespt.com
Contact:+86-752-5538396
Address:Guangdong Huizhou China
Doi:10.1021/jo00318a047
(1981)Doi:10.1016/j.ejmech.2021.113835
(2021)Doi:10.1021/ja061256t
(2006)Doi:10.1016/S0040-4039(00)78602-3
(1980)Doi:10.1016/j.saa.2016.12.005
(2017)Doi:10.1002/jms.652
(2004)
