Journal of the Chemical Society. Perkin transactions I p. 1407 - 1413 (1980)
Update date:2022-08-04
Topics:
Bowman, W. Russell
Richardson, Geoffrey D.
α-Nitrosulphides were prepared by SRN1 reaction of 2-bromo-2-nitropropane with thiolate anions, and by SN2 attack of sodium 2-nitropropan-2-ide on symmetrical disulphides.The α-nitrosulphides undergo radical-nucleophilic substitution (SRN1) by nitronate, sulphinate, and malonate anions, but not by thiolate anions.
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