Journal of the Chemical Society. Chemical communications p. 246 - 247 (1980)
Update date:2022-08-02
Topics:
Barton, Derek H. R.
Lester, David J.
Motherwell, William B.
Papoula, M. Teresa Barros
Further examples of the selectivity of pentavalent triaryl-organobismuth oxidants are presented; deuterium labelling studies have established that the mechanism of oxidation of allylic alcohols by these reagents involves, to some extent, cleavage of the bismuth-aryl bond; several reactions involving the synthetically useful transfer of an aryl group from bismuth to nitrogen and to carbon are described.
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