EPIMERIC 2-NORBORNYL CATIONS IN THE SOLVOLYSIS OF 6-exo- AND 6-endo-SUBSTITUTED 2-exo-NORBORNYL p-TOLUENESULFONATES

DOI: 10.1016/0040-4039(81)80009-3

Source and publish data:

Tetrahedron Letters p. 835 - 838 (1981)

Update date:2022-08-04

Topics:

Authors:

Grob, Cyril A.

Guenther, Bettina

Hanreich, Reinhard

Walder, Adrian

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(81)80009-3

Solvolysis of 6-exo- and 6-endo-substituted 2-exo-norbornyl tosylates 1 and 3, respectively, yields identical or different product mixtures depending on the inductive effect of the substituent, indicating that induction involves graded ?-participation.

Full text of DOI:10.1016/0040-4039(81)80009-3

Products guided by the article

Product name:2-endo-isopropyl-2-exo-norbornanol

Cas No:75600-36-1

R&D Labs maybe for 75600-36-1

GIHI CHEMICALS CO.,LIMITED

Contact:+86-571-86217390

Address:No.567 Dengcai Street,Sandun,Westlake District,Hangzhou310030,Zhejiang,China.
Zibo Xiaoguang Chemical Material Co., Ltd

Contact:15954099116

Address:Boshan Development Zone
ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town
Hangzhou LINGEBA Technology Co., Ltd.

Contact:+0086-571-87389059

Address:Office 1-913,NewYouth Plaza, GongShu Area, HangZhou,ZheJiang,P.R.China
HAORUI ENTERPRISES LLC

Contact:(1) 206-3550089

Address:5115 NE 8TH PL, Renton, WA 98059 USA

Relevant to this article

Urea-tetrahydrobenzoxanthene receptors for carboxylic acids

Doi:10.1016/j.tet.2004.03.015
(2004)
2-Amino-4-chloro-5-formyl-6-[methyl(2-methylphenyl)amino]pyrimidine and 2-amino-4-chloro-5-formyl-6[(2-methoxyphenyl)methylamino]pyrimidine are isostructural and form hydrogen-bonded sheets of R₂²(8) and R₆⁶(32)

Doi:10.1107/S0108270108040481
(2009)
Chelating or bridging Pd(ii) and Pt(ii) metalloligands from the functional phosphine ligand N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine. New heterometallic Pd(ii)/Pt(ii) and Pt(ii)/Au(i) complexes

Doi:10.1039/c0dt01782e
(2011)
Electrophilic ring opening of oxazolines derived from serine and threonine: A practical entry to N(N)-protected β-halogeno α-aminoesters

Doi:10.1016/S0957-4166(98)00002-0
(1998)
Copper-catalyzed decarboxylative C-P cross-coupling of alkynyl acids with H-phosphine oxides: A facile and selective synthesis of (E)-1-alkenylphosphine oxides

Doi:10.1021/ol502009b
(2014)
Stereocontrolled synthesis of Z-dienes via an unexpected pericyclic cascade rearrangement of 5-amino-2,4-pentadienals

Doi:10.1021/ja8028125
(2008)

Article Doi