EPIMERIC 2-NORBORNYL CATIONS IN THE SOLVOLYSIS OF 6-exo- AND 6-endo-SUBSTITUTED 2-exo-NORBORNYL p-TOLUENESULFONATES

DOI: 10.1016/0040-4039(81)80009-3

Source and publish data:

Tetrahedron Letters p. 835 - 838 (1981)

Update date:2022-08-04

Topics:

Authors:

Grob, Cyril A.

Guenther, Bettina

Hanreich, Reinhard

Walder, Adrian

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Article abstract of DOI:10.1016/0040-4039(81)80009-3

Solvolysis of 6-exo- and 6-endo-substituted 2-exo-norbornyl tosylates 1 and 3, respectively, yields identical or different product mixtures depending on the inductive effect of the substituent, indicating that induction involves graded ?-participation.

Full text of DOI:10.1016/0040-4039(81)80009-3

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