Journal of Organometallic Chemistry p. 253 - 260 (1980)
Update date:2022-08-05
Topics: Derivative SYNTHESE
Herberich, G. E.
Buller, B.
Hessner, B.
Oschmann, W.
Analytically pure, dark blue pentaphenylborole (PPB) can be synthesized from 1,1-dibutyl-2,3,4,5-tetraphenylstannole and C6H5BCl2 in toluene in 95percent yield.Reduction of PPB with elemental potassium in THF produces brownish red K2a toluene solution of (C5H5)Co(CO)2 and PPB and by ligand substitution reaction from Pt(COD)2 and PPB respectively.
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Doi:10.1021/jo00316a034
(1981)Doi:10.1016/S0008-6215(00)85433-6
(1980)Doi:10.1246/cl.1980.1131
(1980)Doi:10.1021/ja00545a017
(1980)Doi:10.1248/cpb.29.2161
(1981)Doi:10.1039/P19800002331
(1980)
