
Journal of Organometallic Chemistry p. 37 - 40 (1980)
Update date:2022-08-05
Topics:
Pannell, Keith H.
The complexes (η5-C5H5)Fe(CO)2PbR3 (R=Me and Et) have been synthesized and characterized.The trimethyllead complex is extremely labile with respect to thermal and photochemical decomposition that leads to the formation of (Me)4Pb, Pb, and (η5-C5H5)Fe(CO)2Me.This new type of methyl transfer from Pb to Fe does not occur for the triethyllead complex thermally, but does occur to a limited extent photochemically, and helps explain certain zinc treatments for removal of organolead compounds from industrial effluents.
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Doi:10.1039/P29800001473
(1980)Doi:10.1021/ic049625e
(2004)Doi:10.1002/oms.1210200108
(1985)Doi:10.1039/jr9590002654
(1959)Doi:10.1021/ol036228j
(2004)Doi:10.1246/bcsj.53.2570
(1980)